A citizens guide to monitored natural attenuation technologies. Natural attenuation relies on natural processes to decrease or attenuate concentrations of contaminants in soil and groundwater. Biotrends provides an integrated suite of tools for conducting natural attenuation trend analyses, providing a comprehensive data management system for evaluating monitored natural attenuation. This is a software package developed by sandia national laboratories to. Examples of publicdomain software tools for predicting the natural attenuation of organic compounds in. The usepa will be hosting an internet seminar on this updated information on monitored natural attenuation via their contaminated site cleanup information cluin website. Applicability of monitored natural attenuation at radioactively. Monitored natural attenuation mna is ongoing groundwater monitoring and associated field and laboratory work to confirm whether natural attenuation processes are acting at a sufficient rate to protect environmental values and to demonstrate that remedial objectives. Monitored natural attenuation technical guidance nj. Natural attenuation strategy for groundwater cleanup. Monitored natural attenuation when chlorinated solvents are spilled or leak into soil or groundwater, natural processes occur to destroy or alter the chemicals.
It generally describes a range of physical and biological processes, which, unaided by deliberate human intervention, reduce the concentration, toxicity, or mobility of. This document provides technical guidance for evaluating natural attenuation processes in remediating groundwater contaminated with petroleum products. Monitored natural attenuation guidance updated for the 21st. Dissolved gases including fixed o2, n2, co, co2, and ch4, light hydrocarbons, and hydrogen provide information on the progress of remediation. Steven brauner2, eduardo mendez iii 2, and clifton c. Monitored natural attenuation at superfund, rcra corrective action, and underground storage tank sites usepa mna directive. Methodology for estimating times of remediation associated with monitored natural attenuation by francis h. Use of monitored natural attenuation for groundwater. Fact sheet monitored natural attenuation of chlorinated solvents. Where found to be a viable remedy, monitored natural attenuation may be used within the context of a carefully controlled and. Guidance on natural attenuation for petroleum releases. A technical guide for demonstrating monitored natural attenuation of petroleum hydrocarbons in groundwater executive summary natural attenuation na refers to the reduction in quantity and concentration of contaminants over time as a result of naturally occurring physical, chemical and biological processes within soil and groundwater.
Petroleum remediation program minnesota pollution control. Methodology for estimating times of remediation associated with monitored natural attenuation u. The basic physical processes which, unaided by deliberate human intervention, reduce the concentration, toxicity, or mobility of. A decision framework for applying monitored natural. Steven brauner 2, eduardo mendez iii 3, and clifton c. The package has been upgraded with the release of version 2. Nas was designed as a screening tool to estimate times of remediation tors, associated with monitored natural attenuation mna, to lower groundwater contaminant concentrations to regulatory limits. Documenting that a contaminant has disappeared or that the concentration has become very low in groundwater samples is an important piece of information for proving that natural attenuation is working, but it is not sufficient, even at simple gas station sites.
New paradigms, technologies, and applications from rice university. Als environmental provides analytical testing for monitoring intrinsic remediationnatural attenuation mna at sites contaminated with petroleum hydrocarbons and other chemicals. Natural attenuation software nas natural attenuation software nas is a screening tool to estimate remediation timeframes for monitored natural attenuation mna to lower groundwater contaminant concentrations to regulatory limits, and to assist in decisionmaking on the level of source zone treatment in conjunction with mna using sitespecific remediation objectives. Site screening and technical guidance for monitored natural attenuation at doe. Assessment of natural biodegradation at petroleum release sites page 4 guidance document cprp403. Petroleum remediation program minnesota pollution control agency. A decision to rely on natural attenuation processes as part of a siteremediation strategy depends not only on the occurrence of natural attenuation, but also on its effectiveness in meeting sitespecific remediation goals. Equation 1 ispresented ina generalized form, andit is necessary toaddspeci. Natural attenuation software nas is a screening tool to estimate remediation timeframes for monitored natural attenuation mna to lower groundwater contaminant concentrations to regulatory limits, and to assist in decisionmaking on the level of source zone treatment in conjunction with mna using sitespecific remediation objectives. Where found to be a viable remedy, monitored natural attenuation may be used within the context of a carefully controlled and monitored site cleanup approach. Nas natural attenuation software is a software package that provides a decisionmaking framework for determining the time needed to clean up groundwater contamination sites. Scientific software group is the premier provider of groundwater software, environmental software, groundwater modeling software, surface water modeling. It generally describes a range of physical and biological processes, which, unaided by deliberate human intervention, reduce the concentration, toxicity, or mobility of chemical or radioactive contaminants. Use of monitored natural attenuation as a remediation strategy involves filing a formal regulatory application to allow natural biological, chemical, and physical processes to treat groundwater contaminants, and conducting ongoing monitoring to verify that these processes are effective.
Use of monitored natural attenuation for groundwater remediation. Rna is defined in the american society of testing materials astm standard of practice entitled guide for remediation of groundwater by natural attenuation at petroleum release sites. Assessing remedial strategies and estimating timeframes eduardo mendez iii the charles e. Demonstrationoftheuseofmonitorednaturalattenuationas. Geological survey waterresources investigation report 034057, 51 pages published 2003 by francis h. Natural attenuation software nas is a screening tool to estimate remediation time frames for monitored natural attenuation mna to lower groundwater contaminant concentrations to regulatory limits and to assist in decision making on the level of source zone treatment in conjunction with mna, using sitespecific remediation objectives. Monitored natural attenuation mna tool instructions. Natural attenuation relies on natural processes to clean up or attenuate pollution in soil and groundwater. A decision flowchart for the use of monitored natural. Monitored natural attenuation of inorganic contaminants in. Natural attenuation processes occur in most soil and groundwater systems and act, to varying degrees, on all contaminants. Natural attenuation software free download windows version.
Modflow mt3dms, and the natural attenuation software nas. Monitored natural attenuation of mtbe as a risk management option at leaking underground storage tank sites pdf 89 pp, 4. However, the right conditions must exist underground to clean sites properly. Monitored natural attenuation mna tool instructions revised 51520 mna calculation tool.
Monitored natural attenuation mna as a sound remedial alternative at contaminated sites. Monitored natural attenuation risk management research us epa. Mna relies on natural attenuation processes to achieve sitespecific remediation objectives within a reasonable time frame compared to more active approaches. Monitored natural attenuation mna is an important, common groundwater remediation technology used for treating some dissolved groundwater contaminants. Remediation toolkit monitored natural attenuation toolkit. This natural attenuation is recognized by the epa as a viable method of remediation for soil and groundwater. Monitored natural attenuation mna differs slightly from remediation by natural attenuation rna. Whenconsideringmnaasapossibleremediationoptionforapar. A deterministic approach to evaluate and implement monitored. Environmental protection agencys threevolume document for monitored natural attenuation. A citizens guide to monitored natural attenuation the citizens guide series is a set of 22 fact sheets that summarizes cleanup methods used at superfund and other sites. Nas, natural attenuation software, is a software package that provides a. Site remediation program monitored natural attenuation.
April 2005 petroleum remediation program minnesota pollution control agency figure 1, recommended monitoring well network for demonstrating natural attenuation 1 from rifai, h. Learn natural attenuation of groundwater contaminants. Guidance and software for interpretation of compoundspecific isotope analysis data with reactive transport modeling for improved monitored natural attenuation of chlorinated solvent plumes. This worksheet is a simple tool designed to help determine if monitored natural attenuation mna is appropriate as a corrective action method for a site. How to evaluate alternative cleanup technologies for. Natural attenuation software nas is a screening tool to estimate remediation timeframes for monitored natural attenuation mna to lower. If not, cleanup will not be quick enough or complete enough. Cleaning up the large number of groundwater contamination sites is a significant and complex environmental challenge. Monitored natural attenuation is a strategy and a set of procedures used to demonstrate that physiochemical andor biological processes in an aquifer will reduce concentrations of undesirable substances to levels below regulatory concern. Fact sheet monitored natural attenuation of petroleum. This paper describes the development and application of a modeling system called natural attenuation software nas.
A deterministic approach to evaluate and implement monitored natural attenuation for chlorinated solvents exhibit 2. A deterministic approach to evaluate and implement. The software can plot input data and simulation results to aid in decision making. The natural attenuation software screening tool was codeveloped by the u. Examples of publicdomain software tools for predicting the natural attenuation of organic compounds in groundwater. Estimating cleanup times associated with combining source. Mna includes a monitoring component to evaluate the effectiveness of natural attenuation processes over time and should also include triggers and contingencies to address unforeseen problems, such as plume migration. Interested participants can register at the cluin site for the internet seminar to be held on june, 2014 from 1. Natural attenuation software nas is a screening tool to estimate remediation timeframes for monitored natural attenuation mna and to assist in decisionmaking on the level of source zone treatment in conjunction with mna using sitespecific remediation objectives. New version of nas natural attenuation software available. Monitored natural attenuation mna is an important, common. Als environmental provides analytical testing for monitoring intrinsic remediation natural attenuation mna at sites contaminated with petroleum hydrocarbons and other chemicals. Department of civil and environmental engineering virginia polytechnic institute and state university abstract natural attenuation software nas was developed as a screening tool to estimate remediation.
Mna may be a stand alone option or a part of a strategy involving other activities, for instance source treatment. The report refers to and makes use of previously published literature and guidelines, which are considered as key docu. The theories and processes of natural attenuation are dealt with in many references, some of which are listed at the end of this document. Casey 3 abstract natural attenuation processes combine to disperse, immobilize, and biologically transform anthropogenic contaminants, such as petroleum. Nas is designed to make complex analytical and numerical solutions of the tor problem accessible to remedial project managers rpm and their contractors. These processes take place whether or not other active cleanup measures are in place. The term monitored natural attenuation, as used by the epa, refers to the reliance on natural processes to achieve sitespecific remedial objectives.
Evaluation of monitored natural attenuation at petroleum. A comprehensive study of the theory and application of monitored natural attenuation mna as it relates to two widespread groups of contaminants. Epa remedial technology fact sheet epa 600f98022, 1998 this fact sheet explains what monitored natural attenuation means when the term is used to describe a potential strategy to remediate a contaminated site. The worksheet will calculate the decay rate, time to cleanup, cleanup levels, and. The term mna refers to the reliance on natural attenuation processes to achieve the applicable ground water remediation standard. Use of monitored natural attenuation mna for groundwater. Monitored natural attenuation risk management research. Monitorednaturalattenuationmnaisaremediationtechniqueinwhichacontaminatedsiteis cleanedbynaturalprocesses. Methodology for estimating times of remediation associated. This step provides further criteria to confirm whether monitored natural attenuation is likely to be effective. Conceptual model for the brooklawn study site sourcessinks, adsorption, and reaction.
1293 746 648 1405 1512 1063 1374 560 1498 285 1525 1546 1204 1446 14 1367 1463 769 1459 59 101 969 464 644 16 1268 137 1111 615 807 859 708 936